[N′-(1,3-Dioxoindan-2-ylidene)-2-oxidobenzohydrazidato-κ3 O 2,N,O]tripyridinenickel(II) pyridine solvate
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چکیده
In the title compound, [Ni(C(16)H(8)N(2)O(4))(C(5)H(5)N)(3)]·C(5)H(5)N, the Ni(II) atom is six-coordinated by two O atoms and one N atom from the Schiff base ligand and by three N atoms from three pyridine mol-ecules, forming a distorted octa-hedral geometry. The Ni-O(phenolate) bond [1.9750 (16) Å] is shorter than the Ni-O(carbon-yl) bond [2.0840 (16) Å] and the Ni-N bonds (mean 2.120 Å).
منابع مشابه
Benzene-1,3-diammonium bis(pyridine-2,6-dicarboxylato-κ3 O 2,N,O 6)cobaltate(II) pentahydrate
In the title compound, (C(6)H(10)N(2))[Co(C(7)H(3)NO(4))(2)]·5H(2)O, the Co(II) ion is six-coordinated in an N(2)O(4) environment by two pyridine-2,6-dicarboxyl-ate (pydc) ligands, having a distorted octa-hedral geometry. The crystal packing is stabilized by inter-molecular N-H⋯O, O-H⋯O and weak C-H⋯O hydrogen bonds. There are also π-π inter-actions between the pyridine rings of the pydc ligand...
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